BLUE CLARIFIED PP X GRV-TE1-030-SS-BLK PP FR 8-6 LMS-1000

MSDS CWO 1158 ( SEM-PP Conc EXPTL) GRV-NP-043-CU-PROP PP FR 8-6 LMS-1000

Lilac Sky (PP) 2655C GRV-NY-060-CU-Nat PP FR 8-6 LMS-1000

PG 49223 RD PP MSDS GRV-NY-055-CU PG 49206 BU PP

EPS: $2.50 Assumptions • Mid single digit revenue CAGR • Operating margins in mid-range of 2015 targets • No global recession • No investment in incremental PP&S capacity • Housing starts at 85% of 50 year norm by 2015 • Remain comfortably below 3X Net Debt / EBITDA Page 10 2012 Rev: $2.9B Adj. EPS: $1.00 $0.28 $0.36 $0.20 $0.30 $0.40 Q3 '12 Q3 '13 Adjusted EPS $51.8 $72.4 $40.0 $60.0 $80.0 Q3 '12 Q3 '13 Adjusted Operating Income (millions) 40% $31.7 $55.3 $20.0 $40.0 $60.0 Q3 '12 Q3 '13 Specialty Operating Income (millions) Q3 2013 Financial Highlights • Adjusted EPS increased 29% over prior year • Adjusted Operating Income expanded 40% versus Q3 2012 • Specialty operating income up 74% • Revenue increases 43% versus Q3 2012 • Portfolio transformation activities  Completed acquisition of Spartech  Divested non-core Resin Business 29% 74% Page 11 Significant Debt Maturities Other Debt Total Debt at 9/30/13 Less: Cash Net Debt Available Liquidity Cash ABL Availability Total Liquidity Net Debt / EBITDA* = 1.9x $48 $317 $600 $0 $100 $200 $300 $400 $500 $600 $700 $800 2015 2020 2023 Significant Debt Maturities As of September 30, 2013 ($ millions) Page 12 Coupon Rates: 7.500% 7.375% 5.250% Debt Maturities & Liquidity Summary – 9/30/13 $ 965 22 $ 987 323 $ 664 $ 323 308 $631 *TTM 9/30/2013 Cash Balance = $323M Net Debt / EBITDA* = 1.9x • Repurchased 3.8M shares YTD in 2013 • 16.2 million shares are available for repurchase under the current authorization • Repurchased $45 million, par value, of higher coupon bonds YTD Share/Bond Repurchase • Introduced a quarterly dividend in Q1 2011 and increased in Q1 2012 (25%) and Q1 2013 (20%) • Objective of maintaining and growing Dividends • Expanding our sales, marketing, and technical capabilities is top priority • Investing in operational and LSS initiatives (including synergy capture) • North American manufacturing alignment • CAPEX Organic Growth • Targets that expand our: • Specialty offering • End market presence • Geographic footprint • Synergy opportunities • Adjacent material solutions Acquisitions *TTM 9/30/2013 Use of Cash Page 13 Why Invest In PolyOne? Three Months Ended September 30, 2013 Three Months Ended September 30, 2012 (a) Reconciliation to Condensed Consolidated Statements of Income $ EPS $ EPS Net income from continuing operations attributable to PolyOne shareholders $ 23.2 $ 0.24 $ 19.4 $ 0.22 Special items, after tax 10.5 0.11 5.3 0.06 Tax adjustments (b) 1.8 0.01 0.1 - Adjusted net income / EPS $ 35.5 $ 0.36 $ 24.8 $ 0.28 Three Months Ended September 30, Reconciliation to Condensed Consolidated Operating Income 2013 2012 (a) Operating income before special items $ 72.4 $ 51.8 Special items in operating income (10.8) (8.3) Operating income, GAAP $ 61.6 $ 43.5 (a) Adjusted to reflect the resins business as a discontinued operation.

PG 55211.00 RD PP GRV-NP-110-W-Nat-MIL PP FR 8-6 LMS-1000

UV INTERKAL 79 PURPLE PP HM GRV-NY-045-SS-Nat PP FR 8-6 LMS-1000

PG 52314 PEARL WT PP GRV-NY-060-CU-Nat P5 PP FR 8-6 LMS-1000

PG 96230.00 RD PP SL GRV-NJ-112-W-NAT PP FR 8-6 LMS-1000

X GRV-15640-01-1 PP 301 Natl S PP FR 8-6 LMS-1000