Sign, date and return your proxy card and/or voting instruction card to vote by mail. Common shares represented by a properly signed proxy card will be voted in accordance with the choices marked on the card. You will need the 16-digit control number included on your proxy card and/or voting instruction card.

Garratt President, Performance Products and Solutions PolyOne Corporation Page 48 2014 Revenue by Industry Segment 2014 Revenues: $0.8 Billion At a Glance Performance Products & Solutions 80% 14% Latin America 4% Building & 33% Electrical & 1% 11% 5% Transportation 18% Wire & Cable 16% PolyOne Corporation Page 49 What We Have Delivered 4.3% 6.3% 7.2% 7.7% 2011 2012 2013 2014 Operating Margin $28 $39 $56 $63 2011 2012 2013 2014 Operating Income ($M) •Relentless focus on portfolio mix optimization •Lean Six Sigma drives operational excellence • Innovating in new markets such as healthcare •Expanding presence in Mexico and China Performance Products & Solutions PolyOne Corporation Page 50 $96 $109 2006* 2014 To Value Gross Margin ($ in millions) +13% 1,431 1,124 2006* 2014 From Volume… (lbs in millions) -21% Performance Products & Solutions *2006 = Near peak housing PolyOne Corporation Page 51 Accelerating Growth Market Growth/ Megatrends Innovation Collaboration Geographic Expansion Performance Products & Solutions PolyOne Corporation Page 52 Who We Are Growing With Performance Products & Solutions PolyOne Corporation Page 53 Geographic Growth Opportunities Mexico represents growth, spurred by: • Robust demand in Automotive • Re-shoring from Asia • PolyOne collaboration China is a $2B PVC market; 2nd largest in the world: • A new tax license enables domestic (vs. export) business • We have expanded capacity • We are investing in capability Performance Products & Solutions PolyOne Corporation Page 54 Addressable Market ($ millions) $300 $150 $200 Innovation Pipeline Potential Performance Products & Solutions Prototype Frame Opportunity Scale-up & Test Market Build Business Case Commercial Launch Phase 1 Phase 2 Phase 3 Phase 4 Phase 5 0 2 0 1 0 3 0 1 1 1 5 3 1 1 1 Breakthrough Platform Derivative PolyOne Corporation Page 55 Megatrends Aligned with Key End Markets Increasing Energy Efficiency Protecting the Environment Improving Health and Wellness Megatrend End Markets Globalizing and Localizing Health & Wellness Transportation Packaging Consumer Performance Products & Solutions PolyOne Corporation Page 56 Healthcare Solutions LED Lighting Key Initiatives Eco-Conscious Solutions $25M Revenue potential $30M Revenue potential $60M Revenue Potential Performance Products & Solutions PolyOne Corporation Page 57 Platinum Vision 4.3% 6.3% 7.2% 7.7% 10-12% 2011 2012 2013 2014 2020 Platinum Vision World Class Operating Margin Accelerating Growth Performance Products & Solutions Market Growth/ Megatrends Innovation Collaboration Geographic Expansion PolyOne Corporation Page 58 Summary • Business evolution from volume to value • Business is at an inflection point • Growth will be driven by:  Economic & Megatrend alignment  Innovation  Collaboration across PolyOne  Geographic sales expansion in China and Mexico Performance Products & Solutions PolyOne Corporation Page 59 PolyOne Distribution Mark Crist President, Distribution PolyOne Corporation Page 60 At a Glance PolyOne Distribution 15% 52% 2006 2014 Key Suppliers 2014 Revenues: $1.1 Billion ROIC Building & 13% Electrical & 23% 15% 4% 25% http://www.avient.com/Pages/VariationRoot.aspx PolyOne Corporation Page 61 What We Do Processing Expertise World-Class Supply Chain Deep Customer Relationships Market Consultation Right the First Time… Every Time PolyOne Corporation Page 62 What We Have Delivered 2.6% 3.5% 4.6% 6.4% 6.1% 2006 2008 2010 2012 2014 Operating Margin $19 $28 $42 $66 $68 2006 2008 2010 2012 2014 Operating Income ($M) • World class supplier line card • Differentiating with service and operational excellence • Key portfolio additions with DuPont, Bayer and Ineos • Value based selling and discipline PolyOne Distribution PolyOne Corporation Page 63 Accelerating Growth PolyOne Distribution Market Growth/ Megatrends Commercial Investment Cross-Selling & Collaboration Growth in Targeted Areas PolyOne Corporation Page 64 Who We Are Growing With PolyOne Distribution PolyOne Corporation Page 65 Megatrends Aligned with Key End Markets Increasing Energy Efficiency Protecting the Environment Improving Health and Wellness Megatrend End Markets Globalizing and Localizing Health & Wellness Transportation Packaging Consumer PolyOne Distribution PolyOne Corporation Page 66 Geographic Growth Opportunities • Currently 10% of POD’s revenue is generated from Mexico • Existing business is served “from the border” • New Mexico district & warehouse will drive transportation growth in Central Mexico • Expansion in China resulted from growing with our NA HC customers • Investing in sales deployments • Localizing supply • Gaining Share PolyOne Distribution PolyOne Corporation Page 67 Going Beyond Distribution WeatherTech® – Polymer BumpStep® BEDRUG™ – Tri-fold Truck Bed Cover CeQur PaQ – Type 2 Insulin Delivery Device PolyOne Distribution PolyOne Corporation Page 68 Platinum Vision 2.6% 4.6% 6.1% 6.5 - 7.5% 2006 2010 2014 2020 Platinum Vision World Class Distribution Margin Accelerating Growth PolyOne Distribution Market Growth/ Megatrends Commercial Investment Cross-Selling & Collaboration Growth in Targeted Areas PolyOne Corporation Page 69 Summary • Motivated and well trained POD sellers making the calls / collaborating with other PolyOne businesses • Representing a world class supplier line card • Delighted customers and suppliers who choose us to represent them PolyOne Distribution PolyOne Corporation Page 70 Financial Highlights Bradley C.

Fiber-Line™ Swellcoat™ Water Blocking Yarns support 5G antennae, data centers, and backbone cable designs to prevent equipment damage and signal attenuation due to water ingression in the cables. Fiber-Line™ Fiber Optic Cable solutions enhance the performance and prolong the life of FOC with water blocking yarns, strength members, and ripcords, enabling cable manufacturers to optimize slimmer, stronger, cables at longer aerial spans with lower tension—critical for rural FTTH networks.

Weld lines or knit lines 

Flow Lines: near gate points, compromise appearance and aesthetics   Troubleshoot technical issues, such as warping and flow lines 

CLEVELAND, OH – October 31, 2019 – PolyOne has announced the launch of a new website supporting its unique line of Mesaä construction colorants. PolyOne is a key supplier of polymers to the building and construction industry, but our newer line of Mesa construction colorants expands our market presence even further,” said Kevin Jones, general manager, PolyOne Color & Additives, Americas. 

CLEVELAND – June 24, 2020 – PolyOne today launched OnColor™ WC Choice, a new line of cost-effective colorants that reliably achieve the performance levels required in a range of wire and cable applications. We’ve launched the line of OnColor WC Choice colorants to help our customers be more cost competitive without sacrificing quality or convenience,” said Jayson Humble, marketing leader, PolyOne.

Flow Lines: near gate points, compromise appearance and aesthetics   Troubleshoot technical issues, such as warping and flow lines 

Flow Lines: near gate points, compromise appearance and aesthetics   Troubleshoot technical issues, such as warping and flow lines 

Textile manufacturers invest millions of dollars in high-speed spinning lines to push the limits of quality, consistency and production efficiency. Combined, these innovations extended the spinning rods’ durability for textile equipment running at line speeds of up to 20,000 RPM.