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https://www.avient.com/sites/default/files/resources/Novel_Thermoplastic_Elastomers_with_Universal_Bonding_Characteristics.pdf
This
paper introduces novel developments in themoplastic elastomers which have the uniqueness of universally
bonding to non-polar substrates such as polypropylene at the same time exhibiting outstanding bonding
characteristics to various polar substrates.
2
INTRODUCTION
A hard/ soft combination of TPEs and rigid thermoplastics provides differentiations of a product in various
applications (1).
Rigid thermoplastics include both commodity thermoplastics and
engineering thermoplastics, such as polypropylene (PP), polystyrene (PS), high impact polystyrene (HIPS),
polycarbonate (PC), acrynitrile-butadiene-styrene (ABS), poly(ethylene terephthalate) (PET),
poly(methylmethacrylate) (PMMA), styrene acrylonitrile (SAN), poly(phenylene oxide) (PPO), polyamide
(PA), PC/ABS blend and PPO/PS blend etc..
Figure 1 Surface energy of various thermoplastic elastomers with rigid thermoplastics
Figure 2 Schematic diagram of the peel test
Engineering
Plastics
Polyamide 6,6
ABS
Polycarbonate
Acrylic
Polystyrene
Polypropylene
Polyethylene
Elastomers
COPA
TPU
COPE
S-TPE
TPV
mPE
Surface
Energy (mN/m)
46
43
40
37
34
31
28
5
Table 1.
https://www.avient.com/sites/default/files/2020-08/tpes-for-automotive-industry-bulletin.pdf
INDUSTRY BULLETIN
STANDARD UNITS ONFLEX LO 7120-45N
Volatile Organic Compounds VDA 278 ug/g(ppm) 41
Fogging VDA 278 ug/g(ppm) 521
Odor
• Control
• Dry conditions
• Wet conditions
SAE J1351 (15) 1-10 Scale 1
2
1
Compression Set (23°C)
• 22 hours
• 70 hours
ASTM D395 % 14.4
14.6
Capillary Viscosity
• 1341/s
• 11170/s
ASTM D3835 Pa*s 35
7
HVAC SYSTEMS
OnFlex™ LO
• Features: low VOC/FOG, low odor, good compression set, easy processing, overmolds to polypropylene
• Example applications: seals and flaps in heating, ventilation and air conditioning systems
CHARACTERISTICS ONFLEX™
LO
ONFLEX™
AF
TPE
GENERAL
PURPOSE
TPV TPO
Volatile Organic Compounds (VDA 278) Very Low Moderate Moderate Moderate Very Low
Fogging (VDA 278 & DIN 75201) Very Low Moderate Moderate High Very Low
Odor (VDA 270 Requirement ≤3.0) ≤3.0 ≤3.0 >3 >3 ≤3.0
Gloss Level Low Low Low Very Low High
Tactile Feel Grippy Grippy Grippy Grippy Waxy
Pre-Drying Required No No No Yes No
Raw Material Costs $$ $$ $$ $$$ $
Compression Set @ RT Good Good Good Excellent N/A
Compression Set @ ≥70°C Moderate Moderate Moderate Good N/A
UV Resistance Good Excellent Good Good Good
Weatherability Good Excellent Good Good Good
Hardness Range Low to High Low to High Low to High Low to High High
Density (g/ml) 1.15 0.99 0.90–1.20 0.95–0.98 0.90–1.20
GENERAL CHARACTERISTICS COMPARING TPE, TPV, TPO
Grades shown on both pages are representative of solutions manufactured in North America, more grades available globally.
INTERIORS/EXTERIORS
TEMP STANDARD UNITS ONFLEX AF
7210-40B
ONFLEX AF
7210-50B
ONFLEX AF
7210-60B
ONFLEX AF
7210-70B
ONFLEX AF
7210-80B
QUV Exposure
• 1000 Hrs(0.68 W/m2 @ 340nm)
• 2000 Hrs(0.68 W/m2 @ 340nm) 45°C ΔE 0.49
0.38
0.42
0.48
0.21
0.85
0.22
0.14
0.32
0.24
Xenon-Arc Exposure
• 1000 Hrs(0.35 W/m2 @ 340nm) 63°C ΔE 0.63 0.84 0.34 — 0.58
Capillary Viscosity
• 1341/s
• 11170/s
ASTM
D3835 Pa*s 60
11.4
79
15
65
13
48
13.7
73
16
Ozone Resistance ASTM
D1149(16) B Visual No cracks No cracks No cracks No cracks No cracks
Low Temperature Brittleness ISO 812 B °C -63 -62 -62 -62 -62
OnFlex™ AF
• Features: long-term sealing performance, reduced noise and vibration, grippy feel, low gloss, low odor,
excellent UV resistance and weatherability, easy processability, overmolds to polypropylene
• Example applications: trays, door pockets, fasteners, clips, roof rack pads, roof and door trim, and
window encapsulations
The need to innovate is virtually endless.
https://www.avient.com/sites/default/files/resources/FAQs%2520for%2520PolyOne%2520GHS%2520Requirements%2520Ver%252006%2520April%25202015.pdf
We must make changes to our Material Safety Data Sheets (MSDSs), soon to be called Safety Data Sheets
(SDSs) under the new GHS format.
Q8: What changes can be expected on PolyOne’s Safety Data Sheets?
PolyOne FAQs for the Globally Harmonized System (GHS) Safety Data Sheets (SDS) and Product Labeling.
https://www.avient.com/sites/default/files/2020-10/neu-quality-commitment.pdf
as applicable)
4.2.2 Customer Description
4.2.3 Manufacturer’s Product Code
4.2.4 Manufacturer's Lot Number
4.2.5 Quantity and Units (Example 25 lbs.)
4.2.6 Company Name
4.2.7 Date of Manufacture
4.2.8 Expiration Date (as applicable)
5.0 SUPPORTING DOCUMENTATION
5.1 Certification: Each shipment of product will be accompanied by a Certification that, at
the time of shipment, the material conforms to the Product Specifications.
5.1.1 Certification document will include:
5.1.1.1 Customer Part Number
5.1.1.2 Customer Purchase Order Number
5.1.1.3 Customer Material Description
5.1.1.4 Manufacturer's Lot Number
5.1.1.5 Total quantity shipped (with units)
5.1.1.6 Test values (as applicable)
5.1.2 Certification will be sent with each product shipment, addressed to the
Customer’s shipping location and/or electronically sent to appropriate Customer
contact.
5.1.3 The Certification document may contain test values conducted by NEU on the
product for those characteristics listed under certification.
5.2 Safety Data Sheets: A Safety Data Sheet will be made available upon request or may
be available on NEU’s website.
The SDS is supplied to the shipping
location from where the product is ordered.
5.3 Technical Data Sheets: A Technical Data Sheet will be made available on NEU
proprietary technologies upon request.
5.4 Sales Order Confirmation: A documented response confirming acceptance of a
Customer purchase order.