Performance Products & Solutions (PP&S) also achieved a record return on sales of 9.0%. In addition, PP&S led the company in working capital efficiency at 4.6% of sales and did so while maintaining leading levels of customer service, as evidenced by a 96% on- time delivery rate, an all-time high. March 11, 2013 25+38+38 +73+74+95 19+15+9 +56+72+85 Operating Income % Specialty PP&S Distribution   Specialty Platform Operating Income % of Total ROIC** (after-tax) 3.2% 6.1% 3.0% 20% 7% 9.1% 9.0% 6.4% 45% 11% 2015 TARGET 12%–16% 9%–12% 6%–7.5% 65%–75% 15% 0 20 40 60 80 100 120 $ millions SPECIALTY PLATFORM OPERATING INCOME 40+68+70 +86+84+902012 0 10 20 30 40 50 60 % PERCENTAGE SPECIALTY PLATFORM OPERATING INCOME % OF TOTAL* 41+33+35 +70+79+932012 0 1 2 3 4 5 6 7 8 % PERCENTAGE ADJUSTED RETURN ON SALES^ POLYONE STOCK (POL) PERFORMANCE VERSUS S&P 0 .20 .40 .60 .80 1.00 1.20 1.40 $ DOLLARS ADJUSTED EARNINGS PER SHARE† 0 .2 .4 .6 .8 1 1.2 *Operating income excludes corporate operating income SAFETY INJURY INCIDENCE RATE˚ 12.31.09 6.30.10 12.31.10 6.30.11 12.31.11 6.30.12 12.31.12 DATE 200 150 100 50 0 P R C TA G POL S&P 600 CHEMICALS S&P 500 INJURY incidence rate 91+91+71 +54+47+45 ˚Number of injuries per 100 full time associates^Operating income excludes special items and equity income from SunBelt **ROIC is defined as TTM adjusted OI divided by the sum of average debt and equity over a 5 quarter period †EPS excluding special items and equity income from SunBelt POL 173% S&P 600 Chemicals 34% S&P 500 28% 5 Proof of Performance Our values, strategy, commitment and execution are clearly evident in our recent financial and operational performance.

These included headwinds from hydrocarbon based raw material deflation that reduced revenue by nearly $150 million and compressed margins, primarily within our PolyOne Distribution (POD) and Performance Products and Solutions (PP&S) segments. These associates led to an almost immediate impact in POD and PP&S, where sales cycles are often the shortest within the company. STOCK PERFORMANCE PolyOne’s stock performance has significantly outpaced the S&P 500 index and the S&P Mid Cap Chemicals index. 12.31.09 12.31.10 12.31.11 12.31.12 12.31.13 12.31.14 12.31.15 12.31.16 OPERATING INCOME % OF SALES Color, Additives & Inks PP&S Distribution Designed Structures & Solutions 2006 “Where we were” 1.7% 1.1% 5.5% 2.6% N/A 2016 “Where we are” 16.0% 14.3% 11.1% 6.4% -0.9% 2020 Platinum Vision 20% + 20% + 12–14% 6.5–7.5% 8–10% 500 400 300 200 100 P TA G POL S&P MID CAP CHEMICALS S&P 500 L D IV ID D $ /S RETURNING CASH TO SHAREHOLDERS .50 .40 .30 .20 .10 5+30+36+45+59+80+88+95 2.20 2.00 1.80 1.60 1.40 1.20 1.00 .80 .60 .40 .20 ADJUSTED EARNINGS PER SHARE*^ .S .

Geon(TM) V1526-70 White FR Scrim Coat Plast Geon(TM) V1526-22 Forest Green FR Scrim Coa PP FR 8-6 LMS-1000

Performance Products & Solutions (PP&S) achieved a new record for return on sales at 7.2 percent and further reduced its working capital as a percent of sales to 4.3 percent. This strength was most notably evidenced by our hiring last year of Brad Richardson as CFO and Michael Garratt as president of PP&S. PolyOne’s stock performance has significantly outpaced the S&P 500 index and the S&P Mid Cap 400 Chemicals index. 12.31.09 6.30.10 12.31.10 6.30.11 12.31.11 6.30.12 12.31.12 6.30.13 12.31.13 2007 2008 2009 2010 2011 2012 2013 SPECIALTY PLATFORM OPERATING INCOME % OF TOTAL*^ 1.50 1.20 .90 .60 .30 2007 2008 2009 2010 2011 2012 2013 ADJUSTED EARNINGS PER SHARE*† * 2010–2013 Specialty Operating Income is restated for the divestiture of the Resin Business ^Operating Income excludes Corporate Charges * 2010–2013 adjusted EPS is restated for the divestiture of the Resin Business † EPS excluding special items and equity income from SunBelt 2007 2008 2009 2010 2011 2012 2013 * 2010–2013 adjusted return on sales is restated for the divestiture of the Resin Business ° Operating Income as a percentage of sales, excluding special items and equity income from SunBelt ADJUSTED RETURN ON SALES*º 8 6 4 2 P 80 60 40 20 P Operating Income % Specialty PP&S Distribution Specialty Platform Operating Income % of Total ROIC** (after-tax) 2006 1.5% 5.5% 2.6% 6.0% 5.0% 9.4% 7.2% 5.9% 62.0% 9.1% 2015 TARGET 12%–16% 9%–12% 6%–7.5% 65%–75% 15% **ROIC is defined as adjusted OI divided by the sum of average debt and equity over a 5 quarter period 200 160 120 80 40 2007 2008 2009 2010 2011 2012 2013 SPECIALTY PLATFORM OPERATING INCOME* * 2010–2013 Operating Income is restated for the divestiture of the Resin Business 400 300 200 100 P POLYONE STOCK (POL) PERFORMANCE VERSUS S&P POL S&P MID CAP 400 CHEMICALS S&P 500 United States Securities and Exchange Commission Washington, DC 20549 FORM 10-K Í ANNUAL REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the fiscal year ended December 31, 2013 ‘ TRANSITION REPORT PURSUANT TO SECTION 13 OR 15(d) OF THE SECURITIES EXCHANGE ACT OF 1934 For the transition period from to .

Additives and Colorants for PP-R and PP-RCT Pipe Systems PP-R and PP-RCT Pipe & Fittings Matched color references in concentrates suitable for PP-R and PP-RCT

Under the Remafin™ brand name, color masterbatches (color concentrates) are specially formulated for use in polyolefin polymers, including high-density, low-density and linear low-density polyethylene (PE), and polypropylene (PP). PP-R and PP-RCT Pipe & Fittings Matched color references in concentrates suitable for PP-R and PP-RCT

Maxxam™ FR Flame Retardant Formulations provided certified material and added durability to vacuum battery pack and cover Provided a more sustainable solution with 60% recycled content while maintaining the performance characteristics of prime PP

Maxxam™ FR Flame Retardant Formulations provided certified material and added durability to vacuum battery pack and cover Provided a more sustainable solution with 60% recycled content while maintaining the performance characteristics of prime PP

PP FR 8-6 LMS-1000

PP FR 8-6 LMS-1000