Forward – Looking Statements Page 2 • This presentation includes the use of both GAAP (generally accepted accounting principles) and non-GAAP financial measures. Use of Non GAAP Measures Page 3 -150.00% -100.00% -50.00% 0.00% 50.00% 100.00% 150.00% 200.00% 250.00% 300.00% 350.00% PolyOne S&P 500 Strategy and Execution Drive Results Page 4 • Since 2006, PolyOne stock has expanded approximately 300% vs. a 30% increase in the S&P 500 All time closing high of $26.63 May 28, 2013 The World’s Premier Provider of Specialized Polymer Materials, Services & Solutions Four Pillar Strategy Page 5 2013 Portfolio Transformation Highlights • Substantial organic mix improvement drives 29% increase in first quarter EPS – 14th consecutive quarter of double-digit EPS growth • Completed acquisition of Spartech • Announced the creation of a new Specialty segment – Designed Structures and Solutions • Completed the sale of our non-core resin assets • Realigned our Specialty Coatings business into our GCAI segment Page 6 0.12 0.27 0.21 0.13 0.68 0.82 1.00 2.50 $0.00 $0.25 $0.50 $0.75 $1.00 $1.25 $1.50 $1.75 $2.00 $2.25 $2.50 2006 2007 2008 2009 2010* 2011* 2012* 2015 Target Ad ju st ed E ar ni ng s P er S ha re Appliance 6% Building & Construction 13% Wire & Cable Electrical & Electronics 4% Consumer Packaging 18% Industrial 10% Misc. 5% HealthCare Transportation 16% Textiles 1% PP&S 15% Specialty Distribution 25% United States 70% Europe 14% Canada 8% Asia 5% Latin America 3% 2012 Revenues: $4.0 Billion* End Markets* 2012 Revenues: $4.0 Billion* EPS Page 7 * Pro Forma includes FY2012 results for Spartech (11/03/12 YE) and Glasforms & excludes resin assets PolyOne At A Glance * Restated to exclude discontinued operations Old PolyOne Transformation *Operating Income excludes corporate charges and special items **Pro Forma results include Spartech and Glasforms acquisitions, Specialty Coatings reclass and excludes resin assets 2% 34% 43% 45% 60% 65 – 75% 0% 20% 40% 60% 80% 100% 2005 2008 2010 2012 2012PF** 2015 % o f O pe ra tin g In co m e* JV's PP&S Distribution Specialty Specialty OI $5M $46M $87M $114M $150M Target Mix Shift Highlights Specialty Transformation 2015 Target Page 8 2007 Q1 2013 2015 Target 1) Operating Income % Specialty: Global Color, Additives & Inks 4.6% 11.7% 12 – 16% Global Specialty Engineered Materials 1.3% 10.1% 12 – 16% Designed Structures & Solutions -- 4.6% 8 – 10% Performance Products & Solutions 6.1% 8.1% 9 – 12% Distribution 3.0% 6.0% 6 – 7.5% 2) Specialty Platform % of Operating Income 20% 60% 65 – 75% 3) ROIC* (after-tax) 7% 9.2% 15% 4) Adjusted EPS Growth N/A 29% Double Digit Expansion Proof of Performance & 2015 Goals *ROIC is defined as TTM adjusted OI divided by the sum of average debt and equity over a 5 quarter period Page 9 *Percentage of Specialty Platform revenue from products introduced in last five years 19.5% 50.0% 2006 Q1 2013 $20.3 $41.9 2006 2012 14.3% 27.8% 2006 Q1 2013 Research & Development Spending Specialty Platform Vitality Index Progression* Innovation Drives Earnings Growth ($ millions) Specialty Platform Gross Margin % Page 10 Positioned for Strong Growth 2015 Target Rev: $5B Adj. EPS: $2.50 Assumptions • Operating margins in mid-range of 2015 targets • No global recession • No investment in incremental PP&S capacity • Completion of 2-3 midsize accretive acquisitions • Housing starts at 85% of 50 year norm by 2015 • Mid single digit revenue CAGR • Remain comfortably below 3X Net Debt / EBITDA Page 11 2012 Rev: $2.9B Adj.

Forward – Looking Statements Page 2 • This presentation includes the use of both GAAP (generally accepted accounting principles) and non-GAAP financial measures. Use of Non-GAAP Measures Page 3 -150.00% -50.00% 50.00% 150.00% 250.00% 350.00% PolyOne S&P 500 Strategy and Execution Drive Results Page 4 All time closing high of $29.48 August 1, 2013 • 15 consecutive quarters of double digit EPS growth • 42% CAGR adjusted EPS expansion 2006-2012 • YTD stock price has increased 42% versus 20% growth in the S&P • 275% increase in market cap: $0.7b $2.6b since 2006 The World’s Premier Provider of Specialized Polymer Materials, Services & Solutions Four Pillar Strategy Page 5 PP&S 15% Specialty Distribution 25% 0.12 0.27 0.21 0.13 0.68 0.82 1.00 2.50 $0.00 $0.25 $0.50 $0.75 $1.00 $1.25 $1.50 $1.75 $2.00 $2.25 $2.50 2006 2007 2008 2009 2010* 2011* 2012* 2015 Target Ad ju st ed E ar ni ng s P er S ha re Appliance 6% Building & Construction 13% Wire & Cable Electrical & Electronics 4% Consumer Packaging 18% Industrial 10% Misc. 5% HealthCare Transportation 16% Textiles 1% United States 70% Europe 14% Canada 8% Asia 5% Latin America 3% 2012 Revenues: $4.0 Billion* End Markets* 2012 Revenues: $4.0 Billion* EPS Page 6 * Pro Forma includes FY2012 results for Spartech (11/03/12 YE) and Glasforms & excludes discontinued operations PolyOne At A Glance * Restated to exclude discontinued operations Old PolyOne Transformation *Operating Income excludes corporate charges and special items **Pro Forma results include Spartech and Glasforms acquisitions, Specialty Coatings reclass and excludes discontinued operations 2% 34% 43% 45% 60% 65- 75% 0% 20% 40% 60% 80% 100% 2005 2008 2010 2012 2012 PF** 2015 % o f O pe ra tin g In co m e* JV's PP&S Distribution Specialty Specialty OI $5M $46M $87M $114M $150M Target Mix Shift Highlights Specialty Transformation 2015 Target Page 7 2006 H1 2013 2015 Where we were Where we are Organic Consolidated Target 1) Operating Income % Specialty: Global Color, Additives & Inks 1.7% 12.7% 12.6% 12 – 16% Global Specialty Engineered Materials 1.1% 10.9% 9.2% 12 – 16% Designed Structures & Solutions — — 4.4% 8 – 10% Performance Products & Solutions 5.4% 8.1% 8.2% 9 – 12% Distribution 2.6% 6.1% 6.1% 6 – 7.5% 2) Specialty Platform % of Operating Income 6.0% 62% 65 – 75% 3) ROIC* (after-tax) 5.0% 9.4% 15% 4) Adjusted EPS Growth N/A 26% Double Digit Expansion Proof of Performance & 2015 Goals *ROIC is defined as TTM adjusted OI divided by the sum of average debt and equity over a 5 quarter period Page 8 *Percentage of Specialty Platform revenue from products introduced in last five years 19.5% 46.5% 2006 Q2 2013 $20.3 $44.7 2006 TTM Q2'13 14.3% 31.1% 2006 Q2 2013 Research & Development Spending Specialty Platform Vitality Index Progression* Innovation Drives Earnings Growth ($ millions) Specialty Platform Gross Margin % Page 9 We are Experts in Polymer Science and Formulation  Polymer Science  Formulation  Chemistry  Processing Inputs  Base Resins  Additives  Modifiers  Colorants Specialized Polymer Materials, Services, and Solutions Expertise Satisfied Consumers PolyOne Customer Innovative Products & Services  Marketplace Demands  Performance Requirements  Value Drivers Page 10 Positioned for Strong Growth 2015 Target Rev: $5B Adj. EPS: $2.50 Assumptions • Operating margins in mid-range of 2015 targets • No global recession • No investment in incremental PP&S capacity • Completion of 2-3 midsize accretive acquisitions • Housing starts at 85% of 50 year norm by 2015 • Mid single digit revenue CAGR • Remain comfortably below 3X Net Debt / EBITDA Page 11 2012 Rev: $2.9B Adj.

Has an immediate family member who is a current partner of the Company’s internal or external auditor, or who is a current employee of the Company’s internal or external auditor and personally works on the Company’s audit; 2 E. Has been, or has an immediate family member who has been, within the last three years, a partner or employee of the Company’s internal or external auditor and personally worked on the Company’s audit within that time; F. All such actions, interpretations and determinations that are done or made by the Board in good faith will be final, conclusive and binding. 2.

AIRCRAFT INTERIOR OEM A I R C R A F T F L O O R I N G • Meet aircraft flammability requirements (FAA) • Provide flame retardance and smoke mitigation • Maintain physical properties • Control viscosity and allow enhanced processability • Retain product integrity as contaminant free • Provide product traceability • Provided strong global EHS and regulatory support to minimize risk • Offered a solution to improve quality consistency and control viscosity • Enhanced mixing capability and improved processing temperature and imprint hold • Allowed greater security of supply with multiple manufacturing locations • Provided an integrated solution of plastisols and pigment dispersions that met traceability requirements with JIT delivery KEY REQUIREMENTS QUALITY + PERFORMANCE WHY AVIENT?

CABLE MANUFACTURER H I G H F L A M E R E T A R D A N T S H E A T H F O R R I S E R C A B L E S • Fire performance: CPR classification Dca s1 a1 d0 at a thickness of 350µm • Low shrinkage • Water, UV and chemical resistance • Low CoF • Reduced cable weight by decreasing the jacket thickness from 550µm to 350µm • Provided required CPR classification at a reduced thickness allowing installation in homes and buildings in between walls and floors • Increased cable lifetime due to improved chemical and UV resistance • Enabled fast cable processing ECCOH™ 5702 SEPAP Formulation KEY REQUIREMENTS WHY AVIENT?

EUROPEAN CABLE MANUFACTURER J A C K E T F O R T H I N F T T H C A B L E S • FTTH jacket material for cables installed in premises where no duct and little space is available • Superior crush resistance for small diameter cables • UV and chemical resistance including solvents, oil, acid and bases • Utilized formulation expertise to provide a solution with the desired combination of performance characteristics • Provided superior UV and chemical resistance, increasing cable lifetime • Reduced attenuation loss due to better crush resistance • Enabled the required flexibility and reduced cable weight ECCOH™ 5970 Formulation KEY REQUIREMENTS WHY AVIENT?

GLOBAL CABLE MANUFACTURER M I C R O M O D U L E S F O R O P T I C A L F I B E R C A B L E S Meet specific standards for stranded, loose tube, optical fiber cable performance and production, including: • High speed processing at a low wall thickness • Good colorability • Resistance to chemicals and filling compounds • UV ageing performance • Low shrinkage • Enabled faster processing speeds and manufacturing consistency with a reliable material, eliminating waste • Enabled easier installation with excellent colorability at low wall thickness • Provided technical support to transfer the product to multiple plants ECCOH LSFOH 6154 UV KEY REQUIREMENTS WHY AVIENT?

LAWN & GARDEN OEM F A N F O R B L O W E R / V A C U U M • Lighter than incumbent magnesium part to improve start- up efficiency and enhance overall user experience • High impact resistance to withstand the effect of fast- moving landscaping debris • Good dimensional stability to meet tight tolerances of assembly • Expertise to guide next-generation product development • Proved material performance success through extensive Mold Flow and FEA simulations to prove concept without prototyping and minimize development costs • Produced material globally to support regional demands • Referred customer to US-based dependable mold shops to support local production Complēt™ MT 40% Long Glass Fiber Impact Modified Formulation KEY REQUIREMENTS WHY AVIENT?

LAWN & GARDEN OEM F A N F O R B L O W E R / V A C U U M • Lighter than incumbent magnesium part to improve start- up efficiency and enhance overall user experience • High impact resistance to withstand the effect of fast- moving landscaping debris • Good dimensional stability to meet tight tolerances of assembly • Expertise to guide next-generation product development • Proved material performance success through extensive Mold Flow and FEA simulations to prove concept without prototyping and minimize development costs • Produced material globally to support regional demands • Referred customer to US-based dependable mold shops to support local production Complēt™ MT 40% Long Glass Fiber Impact Modified Formulation KEY REQUIREMENTS WHY AVIENT?

Biodegradable & compostable BIO FILM BAG MANUFACTURER F L E X I B L E P L A F I L M • Easy film unwinding without optical impairments or mechanical damage • Excellent clarity and transparency in BOPLA applications • Compliant with food contact applications* • Provided a solution to minimize film-to-film surface contact, decreasing the coefficient of friction between layers lying on top of each other • Created a customized formulation by mixing anti- blocking additives and slip agents, maintaining process speed without impacting performance or film quality • Improved handling of the PLA shopping bags, making them easier to open CESA™ & OnCap™ BIO ABSL additives KEY REQUIREMENTS WHY AVIENT?